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Nucleic Acids Symposium Series 2004 48(1):1-2; doi:10.1093/nass/48.1.1
© 2004 by Oxford University Press
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Synthesis of novel 4'-modified neplanocin A analogues based on radical-mediated sulfur-extrusive stannylation

Hiroki Kumamoto, Kazuki Deguchi, Nonoko Takahashi and Hiromichi Tanaka

School of Pharmaceutical Sciences, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo 142-8555, Japan

A new approach was developed for the synthesis of 4'-modified neplanocin A, as potential inhibitors against S-adenosyl-L-homocysteine hydrolase. Vinylstannane derivative 5, a key intermediate in the present approach, was prepared by radical-mediated sulfur-extrusive stannylation.


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