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Nucleic Acids Symposium Series 2004 48(1):5-6; doi:10.1093/nass/48.1.5
© 2004 by Oxford University Press
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Molecular design of novel spin-labeled nucleosides directly attached base moiety

Toshiyuki Kaneko, Toshinori Katsurabara, Yasuhiro Matsui, Mariko Aso, Noboru Koga and Hiroshi Suemune

Graduate School of Pharmaceutical Sciences, Kyushu Univerisity, Maidashi, Higashi-ku, Fukuoka 812-8582, Japan

N-tert-Butylaminoxyl nucleosides (1 and 2) were synthesized starting from 6-chloropurine derivative (3). These compounds are expected as a new tool to elucidate structure of DNA. Their properties and pH-dependent change of EPR spectra were studied.


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