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Nucleic Acids Symposium Series 2008 52(1):547-548; doi:10.1093/nass/nrn277
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© 2008 Oxford University Press

This article appears in the following Nucleic Acid Symposium Series issue: Joint Symposium of the 18th International Roundtable on Nucleosides, Nucleotides and Nucleic Acids and the 35th International Symposium on Nucleic Acids Chemistry [View the issue table of contents]

Synthesis of some derivatives of 3'-C-methyl pyrimidine nucleosides

Mohamed Aljarah, Christophe Mathé and Christian Périgaud*

Institut des Biomolécules Max Mousseron (IBMM), UMR 5247 CNRS-UM 1-UM 2, Université Montpellier 2, case courrier 1705, Place E. Bataillon, 34095 Montpellier cedex 05, France

*Corresponding Author. E-mail: perigaud{at}univ-montp2.fr

Abstract

Attempts for the synthesis of 2'-deoxy-2'-fluoro nucleoside derivative of 3'-C-methyluridine were reported. The corresponding parent nucleoside was chosen as the starting material. However, the 2'-deoxy-2'-fluoro nucleoside was not obtained. Nevertheless, the new and unexpected nucleoside derivatives obtained as well as some proposals of mechanism regarding their formation will be presented.


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